标题：Adsorption Synthesis of Iron Oxide-Supported Gold Catalyst under Self-Generated Alkaline Conditions for Efficient Elimination of Carbon Monoxide
作者： Pan, Feng; Zhang, Weidong; Ye, Yuxiao; Huang, Yixuan; Xu, Yanzhe; Yuan,Yufeng; Wu, Feng; Li, Jinjun
来源出版物：CATALYSTS卷：8 期：9 文献编号：357 DOI： 出版年：SEP 2018
摘要：Goethite- and hematite-supported highly dispersed gold catalysts for carbon monoxide oxidation were synthesized by gold precursor adsorption onto the support materials in self-generated alkaline solutions. The support materials were prepared by reacting iron nitrate with excess sodium hydroxide. The residual minor alkali incorporated into the support could provide suitable alkaline conditions at approximately pH 8 for the hydrolysis of tetrachloroaurate anions and the subsequent adsorption process. Gold species underwent autoreduction to achieve activation during the synthesis. An increase in pH or temperature to 80 degrees C decreased the gold loading of the catalysts. The optimal catalysts could achieve complete oxidation of carbon monoxide at -20 degrees C.
作者关键词： adsorption; iron oxide; gold; carbon monoxide; catalytic oxidation
通讯作者地址：Li, JJ (reprint author), Wuhan Univ, Sch Resources & Environm Sci, Wuhan 430079, Hubei, Peoples R China.
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地址： [Pan, Feng; Zhang, Weidong; Ye, Yuxiao; Huang, Yixuan; Xu, Yanzhe; Yuan, Yufeng; Wu, Feng; Li, Jinjun] Wuhan Univ, Sch Resources & Environm Sci, Wuhan 430079, Hubei, Peoples R China.
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