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张晖实验室论文在INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH刊出
发布时间:2014-02-21 08:47:19     发布者:yz     浏览次数:

标题:Degradation of Toluene by a Selective Ferrous Ion Activated Persulfate Oxidation Process作者:Long, Anhua; Lei, Yang; Zhang, Hui

来源出版物:INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 卷:53 期:3 页:1033-1039 DOI:10.1021/ie402633n 出版年:JAN 22 2014

摘要:The Fe2+-activated persulfate (PS) oxidation of toluene was evaluated using single-factor tests and response surface methodology (RSM). The results indicated the degradation efficiency increased as the PS and Fe2+ concentrations increased, while excessive dosages inhibited the degradation efficiency. The pH had an insignificant effect on the degradation of toluene. Based on the RSM optimization approach, the degradation efficiency reached a maximum of 84.4%. The main intermediates were also separated and identified by GC MS, and a plausible degradation pathway of toluene was proposed. Further studies of surfactant recovery from flushing effluents mixed with toluene and surfactant were explored. Compared with the Fe2+/H2O2 process, a great enhancement of the toluene degradation efficiency and lower sodium dodecyl sulfate (SDS) degradation efficiency were obtained by the Fe2+/PS process. The results demonstrated that the Fe2+/PS selective oxidation process could be used for SDS recovery and for the degradation of contaminants present in soil flushing effluents.

入藏号:

文献类型:Article

语种:English

扩展关键词:RESPONSE-SURFACE METHODOLOGY;AQUEOUS-SOLUTIONS; CONTAMINATED SOIL;BTEX CONTAMINATION;LANDFILL LEACHATE; ORGANIC-COMPOUNDS;SULFATE RADICALS; FENTON PROCESS;BISPHENOL-A; OPTIMIZATION

通讯作者地址:Zhang, Hui; Wuhan Univ, Dept Environm Engn, Hubei BiomassResource Chem & Environm Biotechnol, Wuhan 430079, Peoples R China.

电子邮件地址:eeng@whu.edu.cn

地址:

[Long, Anhua; Lei, Yang; Zhang, Hui] Wuhan Univ, Dept Environm Engn, Hubei BiomassResource Chem & Environm Biotechnol, Wuhan 430079, Peoples R China.

[Long, Anhua] Jiangxi Sci & Technol Normal Univ, Nanchang 330013, Jiangxi, Peoples R China.

研究方向:Engineering

ISSN:0888-5885

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